(From what I have read on the internet) the stock 4AGZE clutch comes on at 8" vacuum (water) and switchs off at 10" of vacuum with a slight time delay too (so you don't get rapid off-on switching). I copied this and it switched smoothly and barely noticably.
Previously I had switched the clutch on at over 50% throttle. Not as nice a solution as you could often feel a surge as it came on, but still perfectly ok to daily drive. You had to be a little careful in the wet though.
As for the brake booster, the one-way valve ensures you never have positive pressure in the booster. Manifold vacuum sucks air out of the booster and the valve prevents the reverse. Plus you will always (well, unless you're doing something funny) have manifold vacuum when braking. Forget an electric pump, just connect your booster to the intake manifold with a standard one way valve.